Temperature Dependence of the Band Gap of MnAgIn7S12 Single Crystals


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Abstract

MnAgIn7S12 single crystals 16 mm in diameter and ~40 mm in length are grown by planar crystallization of the melt. It is shown that the material grown crystallizes with the formation of the cubic spinel structure. From the transmittance spectra recorded in the region of fundamental absorption in the temperature range 10–320 K, the band gap Eg of the single crystals and its temperature dependence are determined. The dependence has a shape typical of most semiconductor materials: as the temperature is lowered, the band gap Eg increases. A calculation is carried out, and it is shown that the calculated values are in agreement with the experimental data.

About the authors

I. V. Bodnar

Belarusian State University of Informatics and Radioelectronics

Author for correspondence.
Email: chemzav@bsuir.by
Belarus, Minsk, 220013

B. T. Chan

Belarusian State University of Informatics and Radioelectronics

Email: chemzav@bsuir.by
Belarus, Minsk, 220013

V. N. Pavlovskii

Institute of Physics, National Academy of Sciences of Belarus

Email: chemzav@bsuir.by
Belarus, Minsk, 220072

I. E. Svitsiankou

Institute of Physics, National Academy of Sciences of Belarus

Email: chemzav@bsuir.by
Belarus, Minsk, 220072

G. P. Yablonskii

Institute of Physics, National Academy of Sciences of Belarus

Email: chemzav@bsuir.by
Belarus, Minsk, 220072


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