Formation of the low-resistivity compound Cu3Ge by low-temperature treatment in an atomic hydrogen flux
- Authors: Erofeev E.V.1, Kazimirov A.I.1, Fedin I.V.1, Kagadei V.A.2
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Affiliations:
- Research Institute for Electric Communication Systems
- Research and Production Company “Micran”
- Issue: Vol 50, No 9 (2016)
- Pages: 1236-1240
- Section: Fabrication, Treatment, and Testing of Materials and Structures
- URL: https://journals.rcsi.science/1063-7826/article/view/197926
- DOI: https://doi.org/10.1134/S1063782616090086
- ID: 197926
Cite item
Abstract
The systematic features of the formation of the low-resistivity compound Cu3Ge by low-temperature treatment of a Cu/Ge two-layer system in an atomic hydrogen flux are studied. The Cu/Ge two-layer system is deposited onto an i-GaAs substrate. Treatment of the Cu/Ge/i-GaAs system, in which the layer thicknesses are, correspondingly, 122 and 78 nm, in atomic hydrogen with a flux density of 1015 at cm2 s–1 for 2.5–10 min at room temperature induces the interdiffusion of Cu and Ge, with the formation of a polycrystalline film containing the stoichiometric Cu3Ge phase. The film consists of vertically oriented grains 100–150 nm in size and exhibits a minimum resistivity of 4.5 µΩ cm. Variations in the time of treatment of the Cu/Ge/i-GaAs samples in atomic hydrogen affect the Cu and Ge depth distribution, the phase composition of the films, and their resistivity. Experimental observation of the synthesis of the Cu3Ge compound at room temperature suggests that treatment in atomic hydrogen has a stimulating effect on both the diffusion of Cu and Ge and the chemical reaction of Cu3Ge-compound formation. These processes can be activated by the energy released upon the recombination of hydrogen atoms adsorbed at the surface of the Cu/Ge/i-GaAs sample.
About the authors
E. V. Erofeev
Research Institute for Electric Communication Systems
Author for correspondence.
Email: erofeev@micran.ru
Russian Federation, Tomsk, 634034
A. I. Kazimirov
Research Institute for Electric Communication Systems
Email: erofeev@micran.ru
Russian Federation, Tomsk, 634034
I. V. Fedin
Research Institute for Electric Communication Systems
Email: erofeev@micran.ru
Russian Federation, Tomsk, 634034
V. A. Kagadei
Research and Production Company “Micran”
Email: erofeev@micran.ru
Russian Federation, Tomsk, 634045