Synthesis and Comparison of the Electrical Properties of Polyaniline and Poly[(N-2-hydroxyethyl)aniline]
- 作者: Khadieva A.1, Gorbachuk V.1, Latypov R.1, Stoikov I.1
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隶属关系:
- Kazan Federal University
- 期: 卷 53, 编号 16 (2019)
- 页面: 2090-2093
- 栏目: Nanostructures Technology
- URL: https://journals.rcsi.science/1063-7826/article/view/207594
- DOI: https://doi.org/10.1134/S1063782619120133
- ID: 207594
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详细
Supramolecular structures (domains, associates, nanoparticles) based on conjugated polymers are attractive basis for creating new materials for use in modern electronics. In this work we propose a mechanochemical method of synthesis of electrochemically active aniline- and N-(2-hydroxyethyl)aniline-based polymers. The effect of hydroxyethyl moieties on self-assembly of nanoparticles has been studied. Methods of dynamic light scattering and transmission electron microscopy have shown formation of nanosized particles of polyaniline and submicron particles of poly[(N-2-hydroxyethyl)aniline]. The electrical properties of materials were investigated: conductivity of polyaniline is 0.14 Sm/cm, which is constant over a wide range of temperatures and frequencies; conductivity of poly[(N-2-hydroxyethyl)aniline] is in range 2 × 10–9–1 × 10–6 Sm/cm, which strongly depends on temperature and alternating current frequency.
作者简介
A. Khadieva
Kazan Federal University
Email: ivan.stoikov@mail.ru
俄罗斯联邦, Kazan
V. Gorbachuk
Kazan Federal University
Email: ivan.stoikov@mail.ru
俄罗斯联邦, Kazan
R. Latypov
Kazan Federal University
Email: ivan.stoikov@mail.ru
俄罗斯联邦, Kazan
I. Stoikov
Kazan Federal University
编辑信件的主要联系方式.
Email: ivan.stoikov@mail.ru
俄罗斯联邦, Kazan