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Vol 124, No 5 (2023)

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ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА

Phase Transitions in a Frustrated Four-Vertex Potts Model on a Hexagonal Lattice in a Magnetic Field

Ramazanov M.K., Murtazaev A.K., Magomedov M.A., Mazagaeva M.K.

Abstract

The effect of a magnetic field on the phase transitions of a two-dimensional frustrated Potts model with the number of spin states q = 4 on a hexagonal lattice was studied by the Monte Carlo method. The studies were carried out for a wide range of magnetic field strength. The magnetic structures of the ground state in this range have been obtained. The dependence of the magnetization on the magnetic field has been constructed. It has been found that an external magnetic field leads to a first-order phase transition. It is shown that a strong magnetic field removes the degeneracy of the ground state and suppresses the phase transition in the system

Fizika metallov i metallovedenie. 2023;124(5):339-346
pages 339-346 views

Application of Surfactant Activated Milling for Production of Nd–Fe–B Magnets by PLP Technology

Golovnya O.A., Kruchinina K.A., Protasov A.V., Kolodkin D.A., Shitov A.V., Stashkova L.A., Ogurtsov A.V., Taranov D.V.

Abstract

The granulometric composition of Nd–Fe–B powders has been studied in detail after vibratory milling for various times both without and with the addition of siloxane. Sintered magnets were produced by the powder metallurgy method that excluded the pressing of powders. Correlations between the particle size distribution in the initial powders, microstructure of sintered magnets, and their magnetic hysteresis properties have been established. The difference in methods for estimating the size of powder particles by two methods is demonstrated. It is shown that the size distributions of powder particles and magnet grains are bimodal and are described by a superposition of two lognormal distributions.

Fizika metallov i metallovedenie. 2023;124(5):347-356
pages 347-356 views

Influence of the Shape of a Spin-Tunnel Element on the Dependence of Its Magnetoresistance

Amelichev V.V., Vasilyev D.V., Polyakov P.A., Kostyuk D.V., Belyakov P.A., Kasatkin S.I., Polyakov O.P., Kazakov Y.V.

Abstract

A theoretical and experimental study of the dependence of the magnetoresistance for two spin-tunnel junctions (STJs) of ellipsoidal shape has been made. The one-sided homogeneous magnetization reversal mode of an ellipsoidal STJ with different aspect ratios has been experimentally selected. Despite the reverse
inhomogeneous remagnetization, this selection has allowed for the calculation of the magnetic parameters of these elements by developing the Stoner-Wohlfarth theory.

Fizika metallov i metallovedenie. 2023;124(5):357-362
pages 357-362 views

The Electronic Structure and Optical Spectroscopy of ErNi2Mnx Compounds

Knyazev Y.V., Lukoyanov A.V., Kuz’min Y.I., Gerasimov E.G., Mushnikov N.V.

Abstract

The electronic structure and optical properties of nonstoichiometric ErNi2Mnx compounds (with х = 0, 0.5, 1) have been studied. Spin-polarization calculations of the total and partial densities of electron states have been performed in terms of DFT + U method with a correction for strong electronic correlations in the 4f shell of Er in the approximation of ErNi2 – xMnx solid-solution. The peculiarities of transformations of the densities of electron states Have been determined depending on the manganese content. The optical properties of these compounds have been studied over a wide wave length range. The calculated interband optical conductivity spectra have been compared with the dependences obtained experimentally. The origin of the quantum absorption of light is discussed. The plasma and relaxation frequencies of current carriers have been determined.

Fizika metallov i metallovedenie. 2023;124(5):363-368
pages 363-368 views

The Effect of Magnetization Reversal Frequency on the Dynamic Magnetic Hysteresis of a Plate Made of Electrical Stee

Mironyuk N.E., Samatov M.V.

Abstract

Electrodynamic, quasi-static magnetic hysteresis loops and the form of the domain texture of a single-crystal plate have been experimentally obtained. Using mathematical modeling, the change in the dynamic magnetic hysteresis (the magnetic loss energy per unit volume per magnetization reversal cycle) depending on the frequency of the magnetic field is shown. This dependence is due to the inertia of the magnetization of the sample. With a change in frequency, the dynamic magnetic hysteresis can differ significantly from the hysteresis in the case of quasi-static magnetization reversal.

Fizika metallov i metallovedenie. 2023;124(5):369-376
pages 369-376 views

СТРУКТУРА, ФАЗОВЫЕ ПРЕВРАЩЕНИЯ И ДИФФУЗИЯ

The Submonolayer Structure of Ni(111)–(√3 × √3)R30–Pb: Atomic Relaxation and Vibrational Properties

Borisova S.D., Rusina G.G.

Abstract

The results of a theoretical study of the structural and dynamical parameters of surface phases (adsorption phase and surface alloy phase) formed upon the adsorption of 0.33 Pb monolayer on the Ni(111) plane surface are discussed. Calculations were performed using interatomic potentials obtained within the framework of the embedded atom method. The stability of the surface phases was analyzed on the basis of data on the equilibrium atomic configuration, phonon spectra, local density of phonon states, and polarization of localized vibration modes. It is shown that the Pb–Ni surface alloy has the highest dynamic stability among the two possible surface phases.

Fizika metallov i metallovedenie. 2023;124(5):377-383
pages 377-383 views

A Study of the Structural and Energy Properties of (210) and (130) Boundaries in Iron and an Fe–Cr Alloy

Meftakhutdinov R.M., Tikhonchev M.Y., Evseev D.A.

Abstract

The structure and energy properties of symmetric tilt boundaries Σ5 (130)[001] and Σ5 (210)[001] in iron and low-concentration Fe–Cr alloys are investigated from first principles and by the molecular statistics method. It is shown that the boundary strongly changes the interplane distances. The sequence of multilayer
relaxation comprises damped oscillations, gradually decreasing into the grains. The energy for the replacement of iron with chromium atoms near the boundaries is lower than in pure iron. Our calculations indicate the tendency to accumulate Cr atoms and vacancies near the grain boundaries.

Fizika metallov i metallovedenie. 2023;124(5):384-391
pages 384-391 views

Metastable Solid Solutions Formed by Metal Nanoparticles

Volodin V.N., Tuleushev Y.Z., Zhakanbaev E.A., Kalieva A.K.

Abstract

Metastable solid solutions of metals have been obtained using nano- and subnanoparticles. This study shows the effect of the size of atoms of a second element on the multiple increase in solubility and limiting concentration in the solvent, independently of the type of crystal lattice. As an example, the limiting solubility of lead (rPb = 0.935 nm) in niobium (rNb = 0.625 nm) is 23.0 at % and that of cadmium (rCd = 0.1727 nm)
in niobium is 64.0 at %. Further, amorphization of the matrix metal occurs. Compared to metastable solid solutions with the equilibrium systems for which the Hume–Rothery rules work, alloys are formed from metals with different types of crystal lattices. In many cases, a 15% limit of the difference of the sizes of metal atoms is observed. There is a strong discrepancy in the valences of atoms and, in rare cases, in electronegativity. Using analysis of the attributes of the alloys prepared by sputtering of ultradisperse particles, the possibility of expanding the boundaries of the Hume–Rothery criteria should be noted for metastable alloys, in comparison to their equilibrium analogs, which indicates the possibility of deviation from the traditional forecasting the routine of preparation of the material.

Fizika metallov i metallovedenie. 2023;124(5):392-399
pages 392-399 views

Diffusion Characteristics of Clusters of Self-Interstitial Atoms in Vanadium: Molecular Dynamics Data

Demidov D.N., Sivak A.B., Sivak P.A.

Abstract

The temperature dependences of diffusion characteristics of the irradiation-induced defects, namely, clusters of self-interstitial atoms (SIAs) containing up to five atoms, in bcc V (vanadium) have been studied by the method of molecular dynamics in the temperature range of 300–1000 K. The diffusion characteristics include the coefficient of diffusion, the tracer correlation factor, the average displacement before changing the direction of migration, and the frequency of changing the direction of migration. The values of the activation energy of diffusion and the activation energy of changing the direction of migration for the considered types of defects in different temperature ranges have been determined. The dependences of the mechanism of (1D vs 3D) diffusion of SIA clusters on the temperature and cluster size and their possible influence on the parameters of phenomenological models of changes in the microstructure of a material under irradiation (sink strengths of spherical absorbers) are discussed.

Fizika metallov i metallovedenie. 2023;124(5):400-408
pages 400-408 views

The Influence of Frictional Treatment and Low-Temperature Plasma Carburizing on the Structure and Phase Composition of Metastable Austenitic Steel

Savrai R.A., Skorynina P.A., Makarov A.V., Men’shakov A.I., Gaviko V.S.

Abstract

The features of the structure and phase composition of corrosion-resistant austenitic chromium–nickel steel (16.80 wt % Cr, 8.44 wt % Ni) subjected to carburizing in electron beam plasma at temperatures of 350 and 500°C, frictional treatment with a sliding indenter, and a combination of frictional treatment and plasma carburizing have been considered. It has been established that plasma carburizing results in the formation of a modified surface layer consisting of carbon-saturated austenite and carbides (Cr23C6, Fe3C); in this case, the formation of γC-phase occurs only at a temperature of 350°C. The depth of a modified layer increases with an increase in the carburizing temperature. It has been shown that it is useful to perform combined frictional treatment and plasma carburizing at a carburizing temperature of 350°C, since in this case the deformation-induced structure formed as a result of frictional treatment is preserved, and the precipitated carbides remain highly dispersed. In this case, frictional treatment should provide the formation of the deepest
possible diffusion-active layer with a dispersed structure.

Fizika metallov i metallovedenie. 2023;124(5):409-416
pages 409-416 views

The Effect of Boron Addition on the Structure and Mechanical Properties of Cu–Al–Ni–B Alloys with a Thermoelastic Martensitic Transformation

Svirid A.E., Kuranova N.N., Makarov V.V., Pushin V.G.

Abstract

For the first time, data on the peculiarities of the structure of the Cu–Al–Ni–(B) alloys differing in the contents of alloying elements, namely, containing 10–14 wt % aluminum, 3, 4, 4.5 wt % nickel, and 0.02–0.3 wt % boron were obtained using optical, scanning, and transmission microscopy and X-ray diffraction analysis along with measurements of tensile mechanical properties. The effect of boron on the grain size, structure, phase composition, and mechanical properties of the shape-memory alloys has been studied. The localization of aluminum boride precipitates in the structure has been studied, and the effect of grain growth
retardation in (α + β) and β Cu–Al–Ni–B alloys in both cast and heat-treated states has been found.

Fizika metallov i metallovedenie. 2023;124(5):417-427
pages 417-427 views

ПРОЧНОСТЬ И ПЛАСТИЧНОСТЬ

On the Precipitation of the -Phase {111} Al Plates in the Al–Cu–Mg Alloy

Zuiko I.S., Gazizov M.R., Kaibyshev R.O.

Abstract

The precipitation of Ω-phase {111}α plates in the Al–Cu–Mg alloy has been investigated at a Cu/Mg ratio > 10 and low Si content. Unlike Al–Cu–Mg alloys containing Ag, nanoscale plates with an {111}α habit plane has been found for the first time to precipitate in the alloy according to a heterogeneous mechanism, namely, along low-angle boundaries, dislocation lines, and at the θ′-phase/Al-matrix interphase
boundary.

Fizika metallov i metallovedenie. 2023;124(5):428-433
pages 428-433 views

The Effect of Termomechanical Treatment on the Low-Cyclic Fatigue Behavior in an Al–Cu–Mg–Ag Alloy

Gazizov M.R., Gazizova M.Y., Zuiko I.S., Kaibyshev R.O.

Abstract

The mechanical behavior under monotonic and cyclic loadings has been studied in an Al–4.5Cu–0.56Mg–0.77Ag–0.42Mn–0.12Ti–0.05V–0.02Fe (wt %) alloy subjected to thermomechanical treatment (TMT), including a solution heat treatment, quenching in water, uniaxial tension with a plastic strain of 3%, and
peak aging at 190°C (state T83 according to the classification of the Aluminum Association). The T83-ed alloy demonstrates the lowest tensile strength properties in comparison with T6 state (traditional aging) and TMT,
including rolling with a 40%-reduction (T840). Compared to T6 and T840 states, the lowest cyclic strength and cyclic strain hardening coefficients in the Ramberg-Osgood relationship was found to be in T83-ed alloy. To achieve long fatigue life, it is advisable to reduce to the minimum values the degree of intermediate plastic deformation required for straightening Al–Cu–Mg–Ag sheets after their buckling during high-temperature heating for quenching.

Fizika metallov i metallovedenie. 2023;124(5):434-442
pages 434-442 views

A Study of Residual Stresses in Steel Plates Obtained by Laser Deposition Directly on a Rigid Substrate

Rylov S.A., Ivanov S.Y., Zemlyakov E.V., Babkin K.D., Karpov I.D., Em V.T.

Abstract

A neutron diffraction method has been used to study residual stresses in corrosion-resistant martensitic steel AISI 410 plates of the composition (wt %): 0.15 С, 13 Cr, < 1 Mn, < 1 Si, and Fe for balance obtained by direct laser deposition. The plates are deposited on rigid substrates, which are commonly used in practice in the production of large parts. It has been shown that in plates of different thicknesses (2.2 and 7.4 mm) and the same length and width (70 × 30 mm), the patterns of the stress distribution curves are very close, however, the stresses in a 7.4-mm-thick plate are lower than in a 2.2-mm-thick plate. In both plates (2.2/7.4 mm), the maximum normal tensile stresses (~450/350 MPa) are induced near lateral edges of the substrate. The maximum tensile longitudinal stresses (~400/250 MPa) are induced in the middle section of the plate near the upper edge. In the middle section of a 7.4-mm-thick plate, a stress distribution over the thickness is observed: the stresses near the side surfaces are higher than in the middle section. The thickness distribution becomes more uniform by approaching the plate edges. The stress distribution pattern in plates obtained by direct laser deposition strongly depends on the rigidity of the substrate and, to a lesser extent, on the material and deposition technology.

Fizika metallov i metallovedenie. 2023;124(5):443-450
pages 443-450 views

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