Vol 126, No 8 (2025)
ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА
ON THE QUESTION OF THE MECHANISM OF FORMATION AND STABILITY OF THE INDUCED MAGNETIC ANISOTROPY AND DOMAIN STRUCTURE IN SOFT MAGNETIC Fe–18 at%Ga ALLOY SINGLE CRYSTALS
Abstract
The influence of thermomagnetic treatment (TMT) including annealing and cooling of the alloy in a constant magnetic field of 10 kOe applied both along the <100> direction and across one on the magnetostriction of single-crystal samples of the Fe–18 at % Ga alloy has been studied. The samples in the form of thin disks had the “Goss” orientation of the crystallographic axes – {011}<100>. The field dependences of the longitudinal – λ100 and transverse – λ100 ⊥ magnetostriction coefficients were measured before and after TMT. By comparison with literature sources dealing with domain structure, it is shown that magnetoelastic properties correspond to the type of domain structure in alloy samples after slow cooling without external influences (before TMT) and after TMT in a magnetic field parallel or perpendicular to the easy magnetization axis [001] lying in the plane of the sample. Before and after TMT, in a field parallel to the [001] axis, there is a small longitudinal magnetostriction λ100 within a few tens of ppm, while its transverse component λ100 ⊥ is negative and reaches an absolute value of 160–190 ppm. This corresponds to a stripe domain structure, when the magnetization is predominantly oriented parallel to the [001] axis. If during TMT the magnetic field was applied perpendicular to the [001] axis and parallel to the [110] axis, then after TMT a twofold increase in the coefficient λ100 and a 40 percent decrease in λ100 ⊥ are observed. Such changes in magnetoelastic deformation indicate the formation of a transverse domain structure, the domains in which are predominantly magnetized parallel to the [100] and [010] axes. The observed TMT effects and their stability under normal conditions are explained by the directional ordering of Ga–Ga pairs in the bcc lattice of the Fe–Ga alloy.
845-856
FEATURES OF THE ELECTRONIC STATE OF COPPER IONS OF CuBO2 (B = Al, Cr, Fe) COMPOUNDS WITH THE DELAFOSSITE STRUCTURE
Abstract
Nuclear quadrupole resonance (NQR) spectra of 63,65Cu were measured in CuCrO2 and CuAlO2 samples over a wide temperature range (30–380 K). The spectra consist of two Gaussian-shaped lines with a width at half the height of Δ63ν = 30 kHz for CuCrO2 and Δ63ν = 55 kHz for CuAlO2. The frequency of resonance 63,65νQ (T) increases with decreasing temperature and reaches a plateau at Al νQ = 28.29 MHz and Cr 63νQ = 27.11 MHz below 100 K. Analysis of NMR, NQR and structural data of isostructural compounds CuBO2 (B = Al, Cr, Fe) allows us to reasonably assume the presence of hybridized 3dz2-r2 – 4s-orbitals in Cu+ ions.
857-864
THE USAGE OF THE PERMANENT MAGNET ASSEMBLIES FOR SEDIMENTATION OF DISPERSED PARTICLES IN AQUEOUS MEDIA
Abstract
The magnetic separation technology is used in innovative water purification methods for pollutant removal from aqueous media. The efficiency of the magnetic separation depends on the characteristics of the non-uniform magnetic fields generated by magnetic systems, the properties of the aqueous medium, and the magnetic particles.
The influence of gradient magnetic fields generated by permanent magnet assemblies on sedimentation of Fe3O4–SiO2 nanoparticles in aqueous solutions with various viscosities was studied. Numerical modeling was used to calculate the Bz and |Bz·dB/dz| values under the surfaces of a permanent magnet, radial and plane-parallel assemblies made of Sm2Co17 permanent magnets, and soft magnetic steel. It was shown the areas of high values of |Bz·dB/dz| near the surface of the magnetic systems are produced by the assemblies M1 and M2 due to their complex geometries. The magnetic sedimentation efficiency (MSE) of nanoparticles in magnetic field gradients
generated by magnetic systems was studied. The MSE in aqueous solution with a viscosity of 0.89–3.07 mPa·s after exposure time during 30 minutes in the magnetic field of the radial assembly is more than 50%. To achieve the MSE more than 50% at using a plane-parallel assembly, it is required 1 and 5 hours exposure time for aqueous
solutions with a viscosity of 0.89 and 3.07 mPa·s, respectively. The MSE of nanoparticles are higher at using of the assemblies than the permanent magnet. In the areas of high values of |Bz·dB/dz| near the surface of the assemblies the particles velocities are increased, which accelerate the settling of magnetic nanoparticles.
865-872
MODELING THE DEPENDENCE OF THE NÉEL TEMPERATURE OF Cr2CFBr MXene ON STRAIN
Abstract
The effect of lattice strain on the exchange interaction constants of Cr2CFBr MXene was studied using first-principles calculations. Knowledge of the exchange constants made it possible to simulate the dependence of the Néel temperature TN on the lattice strain ε of the MXene using the mean-field method. It was found that with increasing tensile strain, TN changes non-monotonically, reaching a maximum value at ε = 0.1. Compressive strain up to ε = −0.11 monotonically decreases the Néel temperature, but beyond ε < −0.11, it leads to a rapid increase in TN. It is shown that in the Cr2CFBr system, at a strain of ε = −0.11,an “order–order” phase transition occurs, where the Néel-type antiferromagnetic state transforms into a
stripe-type antiferromagnetic state.
873-878
MAGNETIC IMPEDANCE AND PHASE TRANSITIONS
Abstract
The magnetic impedance of wires in the low-frequency regime is theoretically considered. The vicinity of the Curie temperature and spin-orientation transitions are analyzed. It is shown that nonlinear effects are much more sensitive to changes in the magnetic field than linear impedance.
879-884
THE EXACT SOLUTION OF ONE-DIMENSIONAL SPIN MODELS WITH THE MARKOV PROPERTY
Abstract
For one-dimensional spin and pseudospin models that can be mapped to a Markov chain, the free energy of the system at finite temperature can be expressed as a function of bond concentrations. By minimizing the free energy, we can obtain an exact solution for the statistical model. As examples, we consider the one-dimensional Potts model and the dilute Ising chain with interacting impurities.
885-890
СТРУКТУРА, ФАЗОВЫЕ ПРЕВРАЩЕНИЯ И ДИФФУЗИЯ
THE STRUCTURE AND MECHANISM OF CONVERGENCE OF A CYLINDRICAL SHELL MADE OF LOW CARBON STEEL UNDER EXPLOSIVE LOADING
Abstract
An experiment was performed on the convergence of a thick-walled cylindrical shell made of steel 20 under the action of an explosion. The explosion was initiated from eight points evenly spaced along the ring on the
cylindrical surface of the shell. It is established that convergence begins by a solid-state mechanism, with
division into eight fragments according to the number of initiation points. In the process of convergence, the solid-state mechanism is replaced by a hydrodynamic one, in which the shell converges without collapsing, through the formation of ejections (cumulative jets), their expansion and closure in the center of the shell. The change in the convergence mechanism is explained by a decrease in strength and an increase in the ductility of the steel due to an increase in the temperature of the shell during the convergence process. The study of the microstructure showed that high-speed deformation during convergence occurs with the formation of extended bands of localized shear and vortex structures.
891-899
ПРОЧНОСТЬ И ПЛАСТИЧНОСТЬ
A SIMPLE EXPERIMENTAL METHOD FOR MEASURING THE SURFACE TENSION OF LIQUID METALS
Abstract
The possibility of using the sessile drop method to determine the capillary constant and surface tension of metallic melts by measuring the parameters of the drop after its crystallization was considered. The method is quite applicable if the change in the drop's volume resulting from the phase transition is small and lies
within the error of the digital reproduction of its profile. Pure indium, tin, and lead were investigated as examples. The role of flux in the experiments was studied. A new algorithm for determining the capillary constant from the drop profile, based on the solution of the Young–Laplace equation and the Nelder–
Mead simplex optimization method, was developed and numerically implemented.
900-906
MASS TRANSFER MECHANICS PROVIDING ULTRAFINE-GRAINED STRUCTURE FORMATION IN METALS AND ALLOYS
Abstract
The article considers the deformation processes of ultrafine-grained (UFG) structure formation in polycrystalline materials exhibiting superplastic properties, and the theoretical methods of molecular dynamics (MD) and Monte Carlo (MC) for simulating the formation of a nanocrystalline structure. The history
of the interest in grain refinement, caused by the influence of grain size on the strength and superplastic properties of metals and alloys, is briefly described. It is shown that mass transfer underlies the formation of UFG structures, including nanocrystalline ones. In the case of deformation refinement, a new technique for calculating the degree of deformation required to refine the microstructure is proposed. In the case of
theoretical description of nanograin formation using MD and MC methods, the concepts of grain boundary engineering in polycrystalline materials are used, leading to selective mass transfer of grain-boundary atoms forming a dense network of nanoboundaries with high strength and deformation properties. The paper discusses methods of severe plastic deformation and the mechanisms of superplastic deformation.
907-921
EFFECT OF PRE-AGING ON THE THERMAL STABILITY OF ELECTRICAL CONDUCTIVITY AND MECHANICAL PROPERTIES OF THIN ALUMINUM WIRES Al–0.25%Zr–(Si, Er, Hf, Nb)
Abstract
The thermal stability of thin wires made of six aluminum alloys Al–0.25%Zr, additionally alloyed with Si, Er, Hf or Nb, has been studied. Aluminum alloy workpieces were obtained by induction casting, followed by stabilizing annealing (450°C, 1 h) and severe plastic deformation to fragmentation the cast structure. The wire with a diameter of 0.3 mm was made by drawing at room temperature. The thermal stability of the mechanical properties, microhardness, and specific electrical resistivity (SER) of stabilized aluminum wires has been studied. As the annealing temperature increases, a monotonous decrease in the tensile strength, microhardness, and SER of the wires occurs. It is established that the ductility of the wires
depends nonmonotonously (with a maximum) on the annealing temperature. The results of studies of the thermal stability of the properties of stabilized wires are compared with the characteristics of wires that have not been subjected to preliminary stabilizing annealing (450°C, 1 h).
922-935
HIGH-TEMPERATURE SUPERELASTICITY IN [001]-ORIENTED Ni54Mn12Ga25Fe9 SINGLE CRYSTALS UNDER COMPRESSION
Abstract
The high-temperature superelasticity, the temperature dependence of critical stresses for martensite formation, and the yield strength of martensite and austenite in [001]-oriented Ni54Mn12Ga25Fe9 single crystals under compression have been studied. In as-grown and quenched single crystals the yield strength of martensite in single crystals decreased by 640–700 MPa with increases in test temperature, while the strain hardening coefficient increases an order. At high temperatures, this results in the yield strength of
martensite being achieved, the plastic deformation occurring during the martensitic transformation, and the superelasticity range ending. Annealing at 1273 K for 4 hours with following quenching leads to an increase in the yield strength of martensite by 250–350 MPa over the entire temperature range, compared
to as-grown single crystals. This causes an expansion of the superelasticity range in quenched single crystals from ΔTSE = 115 K (308–423 K) to ΔTSE = 155 K (318–473 K).
936-942
EFFECT OF NANO-FACETING ON GRAIN-BOUNDARY SLIP IN Al BICRYSTALS ALLOYED WITH Mg AND Ni
Abstract
The influence of segregations on the processes of grain boundaries (GB)sliding and the energy characteristics of grain boundary shifts for asymmetric GBs of tilt Σ5{010}/{340}<001> and Σ5{110}/{710}<001>
in bicrystals of Al–Mg and Al–Ni alloys was studied using atomistic modeling methods. The energy of generalized grain boundary stacking faults was determined, and preferred directions and the energy barrier for grain boundary sliding were established. It is shown that Ni segregation-induced nano-faceting significantly modifies the grain boundary structure, increasing the slip resistance.
943-949
FILTERS FOR ALBEDO NEUTRON DOSIMETER: MATERIAL SELECTION, CALCULATION, EXPERIMENT
Abstract
Several boron-containing materials and methods for manufacturing neutron filters for albedo neutron luminescent dosimeters are considered. For such filters, experimental and analytical methods have been used to determine the attenuation coefficients for directly incident thermal neutrons, whose impact significantly worsens the metrological characteristics and leads to an overestimation of radiation doses. It was found that filters that meet the requirements for mass thickness and attenuation coefficients can be made from borated ABS plastics, polyethylene and rubber, provided that they contain at least 20% boron carbide or boron nitride.
950-956

