Synthesis, spectral, magnetic, and thermal properties of Ge(IV) tetrachlorocobaltates complexes with 2-hydroxyarylaldehydes pyridinoyl(aminobenzoyl) hydrazones
- 作者: Shmatkova N.1, Seifullina I.1, Vlasenko V.2, Trigub A.3, Levchenkov S.4, Khitrich N.1
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隶属关系:
- Mechnikov Odessa National University
- Research Institute of Physics
- National Research Center “Kurchatov Institute”
- Southern Scientific Center
- 期: 卷 87, 编号 1 (2017)
- 页面: 107-116
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217944
- DOI: https://doi.org/10.1134/S1070363217010170
- ID: 217944
如何引用文章
详细
The interaction in the GeCl4–nicotinoyl(isonicotinoyl, 2-, or 4-aminobenzoyl) hydrazone of 2-hydroxybenz(2-hydroxy-1-naphth)aldehyde (H2L)–CoCl2–methanol systems has resulted in the formation of [Ge(L·H)2][CoCl4]·nCH3OH complexes with germanium chelates [Ge(L·H)2]2+ protonated at the exo chelate nitrogen atom (NPy or NH2) as the cation. The type of electrolytic dissociation and character of thermolysis of the complexes have been revealed. Spectral, thermal, and magnetic properties of the complexes have been studied.
作者简介
N. Shmatkova
Mechnikov Odessa National University
编辑信件的主要联系方式.
Email: nshmatkova@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa, 65082
I. Seifullina
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa, 65082
V. Vlasenko
Research Institute of Physics
Email: nshmatkova@ukr.net
俄罗斯联邦, Rostov-on-Don
A. Trigub
National Research Center “Kurchatov Institute”
Email: nshmatkova@ukr.net
俄罗斯联邦, Moscow
S. Levchenkov
Southern Scientific Center
Email: nshmatkova@ukr.net
俄罗斯联邦, Rostov-on-Don
N. Khitrich
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
乌克兰, ul. Dvoryanskaya 2, Odessa, 65082