Synthesis, spectral, magnetic, and thermal properties of Ge(IV) tetrachlorocobaltates complexes with 2-hydroxyarylaldehydes pyridinoyl(aminobenzoyl) hydrazones
- Авторлар: Shmatkova N.1, Seifullina I.1, Vlasenko V.2, Trigub A.3, Levchenkov S.4, Khitrich N.1
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Мекемелер:
- Mechnikov Odessa National University
- Research Institute of Physics
- National Research Center “Kurchatov Institute”
- Southern Scientific Center
- Шығарылым: Том 87, № 1 (2017)
- Беттер: 107-116
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217944
- DOI: https://doi.org/10.1134/S1070363217010170
- ID: 217944
Дәйексөз келтіру
Аннотация
The interaction in the GeCl4–nicotinoyl(isonicotinoyl, 2-, or 4-aminobenzoyl) hydrazone of 2-hydroxybenz(2-hydroxy-1-naphth)aldehyde (H2L)–CoCl2–methanol systems has resulted in the formation of [Ge(L·H)2][CoCl4]·nCH3OH complexes with germanium chelates [Ge(L·H)2]2+ protonated at the exo chelate nitrogen atom (NPy or NH2) as the cation. The type of electrolytic dissociation and character of thermolysis of the complexes have been revealed. Spectral, thermal, and magnetic properties of the complexes have been studied.
Авторлар туралы
N. Shmatkova
Mechnikov Odessa National University
Хат алмасуға жауапты Автор.
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
I. Seifullina
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
V. Vlasenko
Research Institute of Physics
Email: nshmatkova@ukr.net
Ресей, Rostov-on-Don
A. Trigub
National Research Center “Kurchatov Institute”
Email: nshmatkova@ukr.net
Ресей, Moscow
S. Levchenkov
Southern Scientific Center
Email: nshmatkova@ukr.net
Ресей, Rostov-on-Don
N. Khitrich
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
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