Synthesis, spectral, magnetic, and thermal properties of Ge(IV) tetrachlorocobaltates complexes with 2-hydroxyarylaldehydes pyridinoyl(aminobenzoyl) hydrazones
- Авторы: Shmatkova N.1, Seifullina I.1, Vlasenko V.2, Trigub A.3, Levchenkov S.4, Khitrich N.1
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Учреждения:
- Mechnikov Odessa National University
- Research Institute of Physics
- National Research Center “Kurchatov Institute”
- Southern Scientific Center
- Выпуск: Том 87, № 1 (2017)
- Страницы: 107-116
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217944
- DOI: https://doi.org/10.1134/S1070363217010170
- ID: 217944
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Аннотация
The interaction in the GeCl4–nicotinoyl(isonicotinoyl, 2-, or 4-aminobenzoyl) hydrazone of 2-hydroxybenz(2-hydroxy-1-naphth)aldehyde (H2L)–CoCl2–methanol systems has resulted in the formation of [Ge(L·H)2][CoCl4]·nCH3OH complexes with germanium chelates [Ge(L·H)2]2+ protonated at the exo chelate nitrogen atom (NPy or NH2) as the cation. The type of electrolytic dissociation and character of thermolysis of the complexes have been revealed. Spectral, thermal, and magnetic properties of the complexes have been studied.
Об авторах
N. Shmatkova
Mechnikov Odessa National University
Автор, ответственный за переписку.
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
I. Seifullina
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
V. Vlasenko
Research Institute of Physics
Email: nshmatkova@ukr.net
Россия, Rostov-on-Don
A. Trigub
National Research Center “Kurchatov Institute”
Email: nshmatkova@ukr.net
Россия, Moscow
S. Levchenkov
Southern Scientific Center
Email: nshmatkova@ukr.net
Россия, Rostov-on-Don
N. Khitrich
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Украина, ul. Dvoryanskaya 2, Odessa, 65082
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