Email this article Synthesis, spectral, magnetic, and thermal properties of Ge(IV) tetrachlorocobaltates complexes with 2-hydroxyarylaldehydes pyridinoyl(aminobenzoyl) hydrazones
- Authors: Shmatkova N.V.1, Seifullina I.I.1, Vlasenko V.G.2, Trigub A.L.3, Levchenkov S.I.4, Khitrich N.V.1
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Affiliations:
- Mechnikov Odessa National University
- Research Institute of Physics
- National Research Center “Kurchatov Institute”
- Southern Scientific Center
- Issue: Vol 87, No 1 (2017)
- Pages: 107-116
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217944
- DOI: https://doi.org/10.1134/S1070363217010170
- ID: 217944
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Abstract
The interaction in the GeCl4–nicotinoyl(isonicotinoyl, 2-, or 4-aminobenzoyl) hydrazone of 2-hydroxybenz(2-hydroxy-1-naphth)aldehyde (H2L)–CoCl2–methanol systems has resulted in the formation of [Ge(L·H)2][CoCl4]·nCH3OH complexes with germanium chelates [Ge(L·H)2]2+ protonated at the exo chelate nitrogen atom (NPy or NH2) as the cation. The type of electrolytic dissociation and character of thermolysis of the complexes have been revealed. Spectral, thermal, and magnetic properties of the complexes have been studied.
About the authors
N. V. Shmatkova
Mechnikov Odessa National University
Author for correspondence.
Email: nshmatkova@ukr.net
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
I. I. Seifullina
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
V. G. Vlasenko
Research Institute of Physics
Email: nshmatkova@ukr.net
Russian Federation, Rostov-on-Don
A. L. Trigub
National Research Center “Kurchatov Institute”
Email: nshmatkova@ukr.net
Russian Federation, Moscow
S. I. Levchenkov
Southern Scientific Center
Email: nshmatkova@ukr.net
Russian Federation, Rostov-on-Don
N. V. Khitrich
Mechnikov Odessa National University
Email: nshmatkova@ukr.net
Ukraine, ul. Dvoryanskaya 2, Odessa, 65082
