Synthesis of azamacrocyclic compounds by cyclocondensation of aliphatic α,ω-diamines with acetone


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Resumo

Cyclocondensation of 1,4-diaminobutane and 1,6-diaminohexane with acetone afforded the corresponding 18- and 22-membered trans-azamacrocyclic Curtis compounds in high yield, which contain two azomethine and amine nitrogen atoms. A complex mixture of the products formed containing less than 25% of 16-membered azamacrocyclic cis- and trans-isomers when reacting 1,3-diaminopropane with acetone.

Sobre autores

N. Anisimova

St. Petersburg State University of Industrial Technology and Design

Email: trish@YT4470.spb.edu
Rússia, ul. I. Chernykh 4, St. Petersburg, 198095

E. Khristoforova

St. Petersburg State University of Industrial Technology and Design

Email: trish@YT4470.spb.edu
Rússia, ul. I. Chernykh 4, St. Petersburg, 198095

Yu. Trishin

St. Petersburg State University of Industrial Technology and Design

Autor responsável pela correspondência
Email: trish@YT4470.spb.edu
Rússia, ul. I. Chernykh 4, St. Petersburg, 198095


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2016

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