Email this article Functionalization of 2-Phosphoryl-Substituted Phenols
- Authors: Rogacheva Y.I.1, Baulin D.V.2, Baulin V.E.1,2, Tsivadze A.Y.2
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Affiliations:
- Institute of Physiologically Active Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 89, No 8 (2019)
- Pages: 1595-1603
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223025
- DOI: https://doi.org/10.1134/S1070363219080097
- ID: 223025
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Abstract
The nitration, bromination, diazo coupling, sulfonation, and alkylation of the aromatic ring of a series of 2-phosphoryl-substituted phenols have been studied for the first time. 2,6-Diphosphorylphenols have been obtained for the first time via 1,3-phosphorotropic phosphate-phosphonate rearrangement. The alkylation of 2-(diphenylphosphoryl)phenol at the hydroxy group with 2-bromo- and 2-chloroethanols has been studied under conventional heating and microwave irradiation conditions.
About the authors
Yu. I. Rogacheva
Institute of Physiologically Active Compounds
Email: ximik1988200811@rambler.ru
Russian Federation, Chernogolovka, Moscow oblast
D. V. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: ximik1988200811@rambler.ru
Russian Federation, Moscow
V. E. Baulin
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ximik1988200811@rambler.ru
Russian Federation, Chernogolovka, Moscow oblast; Moscow
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ximik1988200811@rambler.ru
Russian Federation, Moscow
