Functionalization of 2-Phosphoryl-Substituted Phenols

Yu. I. Rogacheva; D. V. Baulin; V. E. Baulin; A. Yu. Tsivadze

doi:10.1134/S1070363219080097

Functionalization of 2-Phosphoryl-Substituted Phenols

Авторлар: Rogacheva Y.¹, Baulin D.², Baulin V.¹^,2, Tsivadze A.²
Мекемелер:
1. Institute of Physiologically Active Compounds
2. Frumkin Institute of Physical Chemistry and Electrochemistry
Шығарылым: Том 89, № 8 (2019)
Беттер: 1595-1603
Бөлім: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223025
DOI: https://doi.org/10.1134/S1070363219080097
ID: 223025

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Аннотация

The nitration, bromination, diazo coupling, sulfonation, and alkylation of the aromatic ring of a series of 2-phosphoryl-substituted phenols have been studied for the first time. 2,6-Diphosphorylphenols have been obtained for the first time via 1,3-phosphorotropic phosphate-phosphonate rearrangement. The alkylation of 2-(diphenylphosphoryl)phenol at the hydroxy group with 2-bromo- and 2-chloroethanols has been studied under conventional heating and microwave irradiation conditions.