Functionalization of 2-Phosphoryl-Substituted Phenols
- Авторы: Rogacheva Y.1, Baulin D.2, Baulin V.1,2, Tsivadze A.2
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Учреждения:
- Institute of Physiologically Active Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 89, № 8 (2019)
- Страницы: 1595-1603
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223025
- DOI: https://doi.org/10.1134/S1070363219080097
- ID: 223025
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Аннотация
The nitration, bromination, diazo coupling, sulfonation, and alkylation of the aromatic ring of a series of 2-phosphoryl-substituted phenols have been studied for the first time. 2,6-Diphosphorylphenols have been obtained for the first time via 1,3-phosphorotropic phosphate-phosphonate rearrangement. The alkylation of 2-(diphenylphosphoryl)phenol at the hydroxy group with 2-bromo- and 2-chloroethanols has been studied under conventional heating and microwave irradiation conditions.
Об авторах
Yu. Rogacheva
Institute of Physiologically Active Compounds
Email: ximik1988200811@rambler.ru
Россия, Chernogolovka, Moscow oblast
D. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: ximik1988200811@rambler.ru
Россия, Moscow
V. Baulin
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ximik1988200811@rambler.ru
Россия, Chernogolovka, Moscow oblast; Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ximik1988200811@rambler.ru
Россия, Moscow