Effect of the Nature of Organic Solvent on the Association of  N -[3-(Dimethylamino)propyl](meth)acrylamides

S. I. Kamorina; A. Yu. Sadikov; D. M. Kamorin; O. A. Kazantsev; M. S. Rumyantsev; M. S. Korotaev; I. N. Postnikova

doi:10.1134/S107036321909010X

Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides

作者: Kamorina S.¹, Sadikov A.¹^,2, Kamorin D.¹^,2, Kazantsev O.¹, Rumyantsev M.¹, Korotaev M.¹, Postnikova I.¹
隶属关系:
1. R. E. Alekseev Nizhny Novgorod State Technical University
2. N. I. Lobachevsky National Research Nizhny Novgorod State University
期: 卷 89, 编号 9 (2019)
页面: 1787-1791
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223069
DOI: https://doi.org/10.1134/S107036321909010X
ID: 223069

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The association of N-[3-(dimethylamino)propyl](meth)acrylamides in tetrachloromethane, tetrahydrofuran, and N, N-dimethylformamide has been studied by means of IR spectroscopy and quantum-chemical simulation at the B3LYP/6-31+G(d,p)/PCM level. The effect of the hydrogen bonding capacity of the solvent on the degree of participation of N-[3-(dimethylamino)propyl](meth)acrylamides in hydrogen bonding with the formation of the amide-solvent type self-associates and heteroassociates has been elucidated.

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N-[3-(dimethylamino)propyl]methacrylamide, N-[3-(dimethylamino)propyl]acrylamide, hydrogen bond, association, solvent effect

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Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides

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关键词

作者简介

S. Kamorina

A. Sadikov

D. Kamorin

O. Kazantsev

M. Rumyantsev

M. Korotaev

I. Postnikova