Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides

Resumo

The association of N-[3-(dimethylamino)propyl](meth)acrylamides in tetrachloromethane, tetrahydrofuran, and N, N-dimethylformamide has been studied by means of IR spectroscopy and quantum-chemical simulation at the B3LYP/6-31+G(d,p)/PCM level. The effect of the hydrogen bonding capacity of the solvent on the degree of participation of N-[3-(dimethylamino)propyl](meth)acrylamides in hydrogen bonding with the formation of the amide-solvent type self-associates and heteroassociates has been elucidated.