Email this article Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides
- Authors: Kamorina S.I.1, Sadikov A.Y.1,2, Kamorin D.M.1,2, Kazantsev O.A.1, Rumyantsev M.S.1, Korotaev M.S.1, Postnikova I.N.1
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Affiliations:
- R. E. Alekseev Nizhny Novgorod State Technical University
- N. I. Lobachevsky National Research Nizhny Novgorod State University
- Issue: Vol 89, No 9 (2019)
- Pages: 1787-1791
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223069
- DOI: https://doi.org/10.1134/S107036321909010X
- ID: 223069
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Abstract
The association of N-[3-(dimethylamino)propyl](meth)acrylamides in tetrachloromethane, tetrahydrofuran, and N, N-dimethylformamide has been studied by means of IR spectroscopy and quantum-chemical simulation at the B3LYP/6-31+G(d,p)/PCM level. The effect of the hydrogen bonding capacity of the solvent on the degree of participation of N-[3-(dimethylamino)propyl](meth)acrylamides in hydrogen bonding with the formation of the amide-solvent type self-associates and heteroassociates has been elucidated.
About the authors
S. I. Kamorina
R. E. Alekseev Nizhny Novgorod State Technical University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
A. Yu. Sadikov
R. E. Alekseev Nizhny Novgorod State Technical University; N. I. Lobachevsky National Research Nizhny Novgorod State University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod
D. M. Kamorin
R. E. Alekseev Nizhny Novgorod State Technical University; N. I. Lobachevsky National Research Nizhny Novgorod State University
Author for correspondence.
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod
O. A. Kazantsev
R. E. Alekseev Nizhny Novgorod State Technical University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
M. S. Rumyantsev
R. E. Alekseev Nizhny Novgorod State Technical University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
M. S. Korotaev
R. E. Alekseev Nizhny Novgorod State Technical University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
I. N. Postnikova
R. E. Alekseev Nizhny Novgorod State Technical University
Email: d.kamorin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
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