Spectral, Acid, and Coordination Properties of Dodecasubstituted Porphyrins
- 作者: Pukhovskaya S.1, Ivanova Y.2, Nam D.1, Semeikin A.1, Syrbu S.1, Mamardashvili N.2
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隶属关系:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- 期: 卷 89, 编号 3 (2019)
- 页面: 586-596
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222830
- DOI: https://doi.org/10.1134/S107036321903040X
- ID: 222830
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详细
The results of investigation of the interrelation between the geometric structure and coordination, acid, and spectral properties of a series of porphyrins with different systems of meso and β substituents are presented. The geometry of polysubstituted porphyrins was optimized at the DFT B3LYP/6-311G level of theory using Gaussian 09. It was shown that the dianionic forms of dodecasubstituted porphyrins hold promise for the development of highly efficient liquid sensors for metal cations.
作者简介
S. Pukhovskaya
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
Yu. Ivanova
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040
Dao Nam
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
A. Semeikin
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, pr. Sheremetevskii 7, Ivanovo, 15300
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
俄罗斯联邦, ul. Akademicheskaya 1, Ivanovo, 153040