Spectral, Acid, and Coordination Properties of Dodecasubstituted Porphyrins
- Authors: Pukhovskaya S.G.1, Ivanova Y.B.2, Nam D.T.1, Semeikin A.S.1, Syrbu S.A.1, Mamardashvili N.Z.2
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Issue: Vol 89, No 3 (2019)
- Pages: 586-596
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222830
- DOI: https://doi.org/10.1134/S107036321903040X
- ID: 222830
Cite item
Abstract
The results of investigation of the interrelation between the geometric structure and coordination, acid, and spectral properties of a series of porphyrins with different systems of meso and β substituents are presented. The geometry of polysubstituted porphyrins was optimized at the DFT B3LYP/6-311G level of theory using Gaussian 09. It was shown that the dianionic forms of dodecasubstituted porphyrins hold promise for the development of highly efficient liquid sensors for metal cations.
Keywords
About the authors
S. G. Pukhovskaya
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: svetlana.puhovskaya@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
Yu. B. Ivanova
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
Dao The Nam
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
A. S. Semeikin
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
S. A. Syrbu
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 15300
N. Zh. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040