Spectral, Acid, and Coordination Properties of Dodecasubstituted Porphyrins
- Авторлар: Pukhovskaya S.1, Ivanova Y.2, Nam D.1, Semeikin A.1, Syrbu S.1, Mamardashvili N.2
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Мекемелер:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Шығарылым: Том 89, № 3 (2019)
- Беттер: 586-596
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222830
- DOI: https://doi.org/10.1134/S107036321903040X
- ID: 222830
Дәйексөз келтіру
Аннотация
The results of investigation of the interrelation between the geometric structure and coordination, acid, and spectral properties of a series of porphyrins with different systems of meso and β substituents are presented. The geometry of polysubstituted porphyrins was optimized at the DFT B3LYP/6-311G level of theory using Gaussian 09. It was shown that the dianionic forms of dodecasubstituted porphyrins hold promise for the development of highly efficient liquid sensors for metal cations.
Негізгі сөздер
Авторлар туралы
S. Pukhovskaya
Ivanovo State University of Chemistry and Technology
Хат алмасуға жауапты Автор.
Email: svetlana.puhovskaya@mail.ru
Ресей, pr. Sheremetevskii 7, Ivanovo, 15300
Yu. Ivanova
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153040
Dao Nam
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Ресей, pr. Sheremetevskii 7, Ivanovo, 15300
A. Semeikin
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Ресей, pr. Sheremetevskii 7, Ivanovo, 15300
S. Syrbu
Ivanovo State University of Chemistry and Technology
Email: svetlana.puhovskaya@mail.ru
Ресей, pr. Sheremetevskii 7, Ivanovo, 15300
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svetlana.puhovskaya@mail.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153040
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