Reaction of 1-(2-Oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with α,β-Unsaturated Aldehydes
- 作者: Sheverdov V.1, Davydova V.1, Nasakin O.1, Maryasov M.1, Dorovatovskii P.2, Khrustalev V.2,3
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隶属关系:
- I. N. Ulyanov Chuvash State University
- National Research Center “Kurchatov Institute”
- Peoples’ Friendship University of Russia (RUDN University)
- 期: 卷 89, 编号 3 (2019)
- 页面: 385-390
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222777
- DOI: https://doi.org/10.1134/S1070363219030034
- ID: 222777
如何引用文章
详细
The reaction of 1-(2-oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with crotonic aldehyde, cinnamic aldehyde, 2-furylacrolein, 3-phenyl-2-propinal, 3-butyl-2-propinal, and R-(−)-myrtenal have been investigated. It has been shown that these reactions proceed through the stage of the formation of 8a-hydroxyhexahydro-2H-chromene-3,3,4,4-tetracarbonitrile, followed by the formation of 10-iminotetrahydro-8a,4-(epoxymethane)chromene-3,3,4(2H,4aH-tricarboritrile. The X-ray diffraction data have suggested that the stereochemical features of the target products are determined by the reaction path.
作者简介
V. Sheverdov
I. N. Ulyanov Chuvash State University
编辑信件的主要联系方式.
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moskoskii pr. 15, Cheboksary, 428015
V. Davydova
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moskoskii pr. 15, Cheboksary, 428015
O. Nasakin
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moskoskii pr. 15, Cheboksary, 428015
M. Maryasov
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moskoskii pr. 15, Cheboksary, 428015
P. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moscow
V. Khrustalev
National Research Center “Kurchatov Institute”; Peoples’ Friendship University of Russia (RUDN University)
Email: SheverdovVP@yandex.ru
俄罗斯联邦, Moscow; Moscow
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