Reaction of 1-(2-Oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with α,β-Unsaturated Aldehydes
- Авторы: Sheverdov V.1, Davydova V.1, Nasakin O.1, Maryasov M.1, Dorovatovskii P.2, Khrustalev V.2,3
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Учреждения:
- I. N. Ulyanov Chuvash State University
- National Research Center “Kurchatov Institute”
- Peoples’ Friendship University of Russia (RUDN University)
- Выпуск: Том 89, № 3 (2019)
- Страницы: 385-390
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222777
- DOI: https://doi.org/10.1134/S1070363219030034
- ID: 222777
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Аннотация
The reaction of 1-(2-oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with crotonic aldehyde, cinnamic aldehyde, 2-furylacrolein, 3-phenyl-2-propinal, 3-butyl-2-propinal, and R-(−)-myrtenal have been investigated. It has been shown that these reactions proceed through the stage of the formation of 8a-hydroxyhexahydro-2H-chromene-3,3,4,4-tetracarbonitrile, followed by the formation of 10-iminotetrahydro-8a,4-(epoxymethane)chromene-3,3,4(2H,4aH-tricarboritrile. The X-ray diffraction data have suggested that the stereochemical features of the target products are determined by the reaction path.
Об авторах
V. Sheverdov
I. N. Ulyanov Chuvash State University
Автор, ответственный за переписку.
Email: SheverdovVP@yandex.ru
Россия, Moskoskii pr. 15, Cheboksary, 428015
V. Davydova
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Россия, Moskoskii pr. 15, Cheboksary, 428015
O. Nasakin
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Россия, Moskoskii pr. 15, Cheboksary, 428015
M. Maryasov
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Россия, Moskoskii pr. 15, Cheboksary, 428015
P. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: SheverdovVP@yandex.ru
Россия, Moscow
V. Khrustalev
National Research Center “Kurchatov Institute”; Peoples’ Friendship University of Russia (RUDN University)
Email: SheverdovVP@yandex.ru
Россия, Moscow; Moscow