Reaction of 1-(2-Oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with α,β-Unsaturated Aldehydes
- Autores: Sheverdov V.1, Davydova V.1, Nasakin O.1, Maryasov M.1, Dorovatovskii P.2, Khrustalev V.2,3
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Afiliações:
- I. N. Ulyanov Chuvash State University
- National Research Center “Kurchatov Institute”
- Peoples’ Friendship University of Russia (RUDN University)
- Edição: Volume 89, Nº 3 (2019)
- Páginas: 385-390
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222777
- DOI: https://doi.org/10.1134/S1070363219030034
- ID: 222777
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Resumo
The reaction of 1-(2-oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with crotonic aldehyde, cinnamic aldehyde, 2-furylacrolein, 3-phenyl-2-propinal, 3-butyl-2-propinal, and R-(−)-myrtenal have been investigated. It has been shown that these reactions proceed through the stage of the formation of 8a-hydroxyhexahydro-2H-chromene-3,3,4,4-tetracarbonitrile, followed by the formation of 10-iminotetrahydro-8a,4-(epoxymethane)chromene-3,3,4(2H,4aH-tricarboritrile. The X-ray diffraction data have suggested that the stereochemical features of the target products are determined by the reaction path.
Sobre autores
V. Sheverdov
I. N. Ulyanov Chuvash State University
Autor responsável pela correspondência
Email: SheverdovVP@yandex.ru
Rússia, Moskoskii pr. 15, Cheboksary, 428015
V. Davydova
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Rússia, Moskoskii pr. 15, Cheboksary, 428015
O. Nasakin
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Rússia, Moskoskii pr. 15, Cheboksary, 428015
M. Maryasov
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Rússia, Moskoskii pr. 15, Cheboksary, 428015
P. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: SheverdovVP@yandex.ru
Rússia, Moscow
V. Khrustalev
National Research Center “Kurchatov Institute”; Peoples’ Friendship University of Russia (RUDN University)
Email: SheverdovVP@yandex.ru
Rússia, Moscow; Moscow
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