Reaction of 1-(2-Oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with α,β-Unsaturated Aldehydes
- Authors: Sheverdov V.P.1, Davydova V.V.1, Nasakin O.E.1, Maryasov M.A.1, Dorovatovskii P.B.2, Khrustalev V.N.2,3
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Affiliations:
- I. N. Ulyanov Chuvash State University
- National Research Center “Kurchatov Institute”
- Peoples’ Friendship University of Russia (RUDN University)
- Issue: Vol 89, No 3 (2019)
- Pages: 385-390
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222777
- DOI: https://doi.org/10.1134/S1070363219030034
- ID: 222777
Cite item
Abstract
The reaction of 1-(2-oxocyclohexyl)ethane-1,1,2,2-tetracarbonitrile with crotonic aldehyde, cinnamic aldehyde, 2-furylacrolein, 3-phenyl-2-propinal, 3-butyl-2-propinal, and R-(−)-myrtenal have been investigated. It has been shown that these reactions proceed through the stage of the formation of 8a-hydroxyhexahydro-2H-chromene-3,3,4,4-tetracarbonitrile, followed by the formation of 10-iminotetrahydro-8a,4-(epoxymethane)chromene-3,3,4(2H,4aH-tricarboritrile. The X-ray diffraction data have suggested that the stereochemical features of the target products are determined by the reaction path.
About the authors
V. P. Sheverdov
I. N. Ulyanov Chuvash State University
Author for correspondence.
Email: SheverdovVP@yandex.ru
Russian Federation, Moskoskii pr. 15, Cheboksary, 428015
V. V. Davydova
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Russian Federation, Moskoskii pr. 15, Cheboksary, 428015
O. E. Nasakin
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Russian Federation, Moskoskii pr. 15, Cheboksary, 428015
M. A. Maryasov
I. N. Ulyanov Chuvash State University
Email: SheverdovVP@yandex.ru
Russian Federation, Moskoskii pr. 15, Cheboksary, 428015
P. B. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: SheverdovVP@yandex.ru
Russian Federation, Moscow
V. N. Khrustalev
National Research Center “Kurchatov Institute”; Peoples’ Friendship University of Russia (RUDN University)
Email: SheverdovVP@yandex.ru
Russian Federation, Moscow; Moscow