Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine
- 作者: Antuf’eva A.1, Akhmatzyanova D.2, Dmitriev M.2, Shklyaeva E.2,3, Abashev G.1,2,3
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隶属关系:
- Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
- Perm State National Research University
- Institute of Natural Sciences
- 期: 卷 88, 编号 6 (2018)
- 页面: 1103-1107
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222235
- DOI: https://doi.org/10.1134/S1070363218060099
- ID: 222235
如何引用文章
详细
A 2,4,6-trisubstituted pyrimidine including a 2-(1H-indol-1-yl) substituent was synthesized by the reaction of 1-ferrocenyl-3-(2-chloroimidazo[1,2-a]pyridin-3-yl)propanone with 2,5-dimethoxytetrahydrofuran. The structure of the synthesized compound was confirmed by IR and 1Н NMR spectroscopy, and X-ray diffraction analysis. It has been shown that the ferrocene-containing compounds synthesized in the present work all demonstrate intramolecular charge transfer which is evidenced by the observation of the corresponding absorption bands with λmaxabs > 480 nm. The oxidation potential of ferrocene (EoxFc) in all the compounds is higher than 700 mV.
作者简介
A. Antuf’eva
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
Email: gabashev@psu.ru
俄罗斯联邦, ul. Akademika Koroleva 3, Perm, 614013
D. Akhmatzyanova
Perm State National Research University
Email: gabashev@psu.ru
俄罗斯联邦, Perm
M. Dmitriev
Perm State National Research University
Email: gabashev@psu.ru
俄罗斯联邦, Perm
E. Shklyaeva
Perm State National Research University; Institute of Natural Sciences
Email: gabashev@psu.ru
俄罗斯联邦, Perm; Perm
G. Abashev
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch; Perm State National Research University; Institute of Natural Sciences
编辑信件的主要联系方式.
Email: gabashev@psu.ru
俄罗斯联邦, ul. Akademika Koroleva 3, Perm, 614013; Perm; Perm