Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine
- Authors: Antuf’eva A.D.1, Akhmatzyanova D.R.2, Dmitriev M.V.2, Shklyaeva E.V.2,3, Abashev G.G.1,2,3
-
Affiliations:
- Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
- Perm State National Research University
- Institute of Natural Sciences
- Issue: Vol 88, No 6 (2018)
- Pages: 1103-1107
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222235
- DOI: https://doi.org/10.1134/S1070363218060099
- ID: 222235
Cite item
Abstract
A 2,4,6-trisubstituted pyrimidine including a 2-(1H-indol-1-yl) substituent was synthesized by the reaction of 1-ferrocenyl-3-(2-chloroimidazo[1,2-a]pyridin-3-yl)propanone with 2,5-dimethoxytetrahydrofuran. The structure of the synthesized compound was confirmed by IR and 1Н NMR spectroscopy, and X-ray diffraction analysis. It has been shown that the ferrocene-containing compounds synthesized in the present work all demonstrate intramolecular charge transfer which is evidenced by the observation of the corresponding absorption bands with λmaxabs > 480 nm. The oxidation potential of ferrocene (EoxFc) in all the compounds is higher than 700 mV.
About the authors
A. D. Antuf’eva
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
Email: gabashev@psu.ru
Russian Federation, ul. Akademika Koroleva 3, Perm, 614013
D. R. Akhmatzyanova
Perm State National Research University
Email: gabashev@psu.ru
Russian Federation, Perm
M. V. Dmitriev
Perm State National Research University
Email: gabashev@psu.ru
Russian Federation, Perm
E. V. Shklyaeva
Perm State National Research University; Institute of Natural Sciences
Email: gabashev@psu.ru
Russian Federation, Perm; Perm
G. G. Abashev
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch; Perm State National Research University; Institute of Natural Sciences
Author for correspondence.
Email: gabashev@psu.ru
Russian Federation, ul. Akademika Koroleva 3, Perm, 614013; Perm; Perm