Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine
- Autores: Antuf’eva A.1, Akhmatzyanova D.2, Dmitriev M.2, Shklyaeva E.2,3, Abashev G.1,2,3
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Afiliações:
- Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
- Perm State National Research University
- Institute of Natural Sciences
- Edição: Volume 88, Nº 6 (2018)
- Páginas: 1103-1107
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222235
- DOI: https://doi.org/10.1134/S1070363218060099
- ID: 222235
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Resumo
A 2,4,6-trisubstituted pyrimidine including a 2-(1H-indol-1-yl) substituent was synthesized by the reaction of 1-ferrocenyl-3-(2-chloroimidazo[1,2-a]pyridin-3-yl)propanone with 2,5-dimethoxytetrahydrofuran. The structure of the synthesized compound was confirmed by IR and 1Н NMR spectroscopy, and X-ray diffraction analysis. It has been shown that the ferrocene-containing compounds synthesized in the present work all demonstrate intramolecular charge transfer which is evidenced by the observation of the corresponding absorption bands with λmaxabs > 480 nm. The oxidation potential of ferrocene (EoxFc) in all the compounds is higher than 700 mV.
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Sobre autores
A. Antuf’eva
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch
Email: gabashev@psu.ru
Rússia, ul. Akademika Koroleva 3, Perm, 614013
D. Akhmatzyanova
Perm State National Research University
Email: gabashev@psu.ru
Rússia, Perm
M. Dmitriev
Perm State National Research University
Email: gabashev@psu.ru
Rússia, Perm
E. Shklyaeva
Perm State National Research University; Institute of Natural Sciences
Email: gabashev@psu.ru
Rússia, Perm; Perm
G. Abashev
Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch; Perm State National Research University; Institute of Natural Sciences
Autor responsável pela correspondência
Email: gabashev@psu.ru
Rússia, ul. Akademika Koroleva 3, Perm, 614013; Perm; Perm