Reactions of Tricymantrenylantimony with Halogens. Synthesis and Structure of Tricymantrenylantimony Dihydroxide
- Авторы: Sharutin V.1, Sharutina O.1, Senchurin V.1, Andreev P.1
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Учреждения:
- National South Ural Research State University
- Выпуск: Том 88, № 5 (2018)
- Страницы: 1049-1052
- Раздел: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222220
- DOI: https://doi.org/10.1134/S1070363218050353
- ID: 222220
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Аннотация
Tricymantrenylantimony dibromide [C5H4Mn(CO)3]3SbBr2 and dichloride [C5H4Mn(CO)3]3SbCl2 were synthesized by the reaction of tricymantrenylantimony with bromine and chlorine in chloroform; the products are transformed into tricymantrenylantimony dihydroxide [C5H4Mn(CO)3]3Sb(OH)2 by the action of potassium hydroxide in ethanol. Antimony atoms in the dihydroxide have a distorted trigonal–pyramidal coordination with oxygen atoms in axial positions [OSbO 175.66(8)°; Sb–O 1.987(2), 2.049(2), Sb–C 2.086(2), 2.101(2), and 2.105(2) Å].
Об авторах
V. Sharutin
National South Ural Research State University
Автор, ответственный за переписку.
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National South Ural Research State University
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
National South Ural Research State University
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080
P. Andreev
National South Ural Research State University
Email: vvsharutin@rambler.ru
Россия, pr. Lenina 76, Chelyabinsk, 454080