Reactions of Tricymantrenylantimony with Halogens. Synthesis and Structure of Tricymantrenylantimony Dihydroxide
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1, Andreev P.V.1
-
Affiliations:
- National South Ural Research State University
- Issue: Vol 88, No 5 (2018)
- Pages: 1049-1052
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222220
- DOI: https://doi.org/10.1134/S1070363218050353
- ID: 222220
Cite item
Abstract
Tricymantrenylantimony dibromide [C5H4Mn(CO)3]3SbBr2 and dichloride [C5H4Mn(CO)3]3SbCl2 were synthesized by the reaction of tricymantrenylantimony with bromine and chlorine in chloroform; the products are transformed into tricymantrenylantimony dihydroxide [C5H4Mn(CO)3]3Sb(OH)2 by the action of potassium hydroxide in ethanol. Antimony atoms in the dihydroxide have a distorted trigonal–pyramidal coordination with oxygen atoms in axial positions [OSbO 175.66(8)°; Sb–O 1.987(2), 2.049(2), Sb–C 2.086(2), 2.101(2), and 2.105(2) Å].
About the authors
V. V. Sharutin
National South Ural Research State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
National South Ural Research State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. S. Senchurin
National South Ural Research State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
P. V. Andreev
National South Ural Research State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080