Reactions of Tricymantrenylantimony with Halogens. Synthesis and Structure of Tricymantrenylantimony Dihydroxide
- Autores: Sharutin V.1, Sharutina O.1, Senchurin V.1, Andreev P.1
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Afiliações:
- National South Ural Research State University
- Edição: Volume 88, Nº 5 (2018)
- Páginas: 1049-1052
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222220
- DOI: https://doi.org/10.1134/S1070363218050353
- ID: 222220
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Resumo
Tricymantrenylantimony dibromide [C5H4Mn(CO)3]3SbBr2 and dichloride [C5H4Mn(CO)3]3SbCl2 were synthesized by the reaction of tricymantrenylantimony with bromine and chlorine in chloroform; the products are transformed into tricymantrenylantimony dihydroxide [C5H4Mn(CO)3]3Sb(OH)2 by the action of potassium hydroxide in ethanol. Antimony atoms in the dihydroxide have a distorted trigonal–pyramidal coordination with oxygen atoms in axial positions [OSbO 175.66(8)°; Sb–O 1.987(2), 2.049(2), Sb–C 2.086(2), 2.101(2), and 2.105(2) Å].
Sobre autores
V. Sharutin
National South Ural Research State University
Autor responsável pela correspondência
Email: vvsharutin@rambler.ru
Rússia, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National South Ural Research State University
Email: vvsharutin@rambler.ru
Rússia, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
National South Ural Research State University
Email: vvsharutin@rambler.ru
Rússia, pr. Lenina 76, Chelyabinsk, 454080
P. Andreev
National South Ural Research State University
Email: vvsharutin@rambler.ru
Rússia, pr. Lenina 76, Chelyabinsk, 454080