Enviar artigo por via de e-mail Solvent Effect on the Rate of Thermal Decomposition of Diacyl Diperoxides
- Autores: Dutka V.1, Midyana G.2, Pal’chikova E.3, Dutka Y.1
-
Afiliações:
- Іvan Franko National University of Lviv
- Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
- Institute of Geology and Geochemistry of Fossil Fuels
- Edição: Volume 88, Nº 4 (2018)
- Páginas: 632-640
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222119
- DOI: https://doi.org/10.1134/S1070363218040047
- ID: 222119
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
The kinetics of thermal decomposition of didecanoyl diperoxyadipate in different organic solvents have been studied. The primary homolytic dissociation of the peroxide bond (O–O) is accompanied by secondary induced chain decomposition processes. The reaction medium affects both the rate of primary homolytic decomposition and secondary decomposition processes. Correlation equations have been proposed for the rate constants of the reactions under study and physicochemical parameters of the solvents.
Sobre autores
V. Dutka
Іvan Franko National University of Lviv
Autor responsável pela correspondência
Email: vdutka@ukr.net
Ucrânia, vul. Universitetskaya 1, Lviv, 79601
G. Midyana
Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
Email: vdutka@ukr.net
Ucrânia, Lviv
E. Pal’chikova
Institute of Geology and Geochemistry of Fossil Fuels
Email: vdutka@ukr.net
Ucrânia, vul. Naukova 3a, Lviv, 79060
Yu. Dutka
Іvan Franko National University of Lviv
Email: vdutka@ukr.net
Ucrânia, vul. Universitetskaya 1, Lviv, 79601
