Email this article Solvent Effect on the Rate of Thermal Decomposition of Diacyl Diperoxides
- Authors: Dutka V.S.1, Midyana G.G.2, Pal’chikova E.Y.3, Dutka Y.V.1
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Affiliations:
- Іvan Franko National University of Lviv
- Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
- Institute of Geology and Geochemistry of Fossil Fuels
- Issue: Vol 88, No 4 (2018)
- Pages: 632-640
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222119
- DOI: https://doi.org/10.1134/S1070363218040047
- ID: 222119
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Abstract
The kinetics of thermal decomposition of didecanoyl diperoxyadipate in different organic solvents have been studied. The primary homolytic dissociation of the peroxide bond (O–O) is accompanied by secondary induced chain decomposition processes. The reaction medium affects both the rate of primary homolytic decomposition and secondary decomposition processes. Correlation equations have been proposed for the rate constants of the reactions under study and physicochemical parameters of the solvents.
About the authors
V. S. Dutka
Іvan Franko National University of Lviv
Author for correspondence.
Email: vdutka@ukr.net
Ukraine, vul. Universitetskaya 1, Lviv, 79601
G. G. Midyana
Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
Email: vdutka@ukr.net
Ukraine, Lviv
E. Ya. Pal’chikova
Institute of Geology and Geochemistry of Fossil Fuels
Email: vdutka@ukr.net
Ukraine, vul. Naukova 3a, Lviv, 79060
Yu. V. Dutka
Іvan Franko National University of Lviv
Email: vdutka@ukr.net
Ukraine, vul. Universitetskaya 1, Lviv, 79601
