Отправить статью по E-mail Solvent Effect on the Rate of Thermal Decomposition of Diacyl Diperoxides
- Авторы: Dutka V.S.1, Midyana G.G.2, Pal’chikova E.Y.3, Dutka Y.V.1
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Учреждения:
- Іvan Franko National University of Lviv
- Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
- Institute of Geology and Geochemistry of Fossil Fuels
- Выпуск: Том 88, № 4 (2018)
- Страницы: 632-640
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222119
- DOI: https://doi.org/10.1134/S1070363218040047
- ID: 222119
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Аннотация
The kinetics of thermal decomposition of didecanoyl diperoxyadipate in different organic solvents have been studied. The primary homolytic dissociation of the peroxide bond (O–O) is accompanied by secondary induced chain decomposition processes. The reaction medium affects both the rate of primary homolytic decomposition and secondary decomposition processes. Correlation equations have been proposed for the rate constants of the reactions under study and physicochemical parameters of the solvents.
Об авторах
V. Dutka
Іvan Franko National University of Lviv
Автор, ответственный за переписку.
Email: vdutka@ukr.net
Украина, vul. Universitetskaya 1, Lviv, 79601
G. Midyana
Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
Email: vdutka@ukr.net
Украина, Lviv
E. Pal’chikova
Institute of Geology and Geochemistry of Fossil Fuels
Email: vdutka@ukr.net
Украина, vul. Naukova 3a, Lviv, 79060
Yu. Dutka
Іvan Franko National University of Lviv
Email: vdutka@ukr.net
Украина, vul. Universitetskaya 1, Lviv, 79601
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