A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties

L. D. Popov; S. A. Borodkin; A. A. Tsaturyan; Yu. P. Tupolova; S. I. Levchenkov; V. V. Minin; A. S. Burlov; Yu. V. Revinskii; I. N. Shcherbakov; E. A. Raspopova

doi:10.1134/S1070363217010121

A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties

Autores: Popov L.¹, Borodkin S.¹, Tsaturyan A.¹, Tupolova Y.¹, Levchenkov S.², Minin V.³, Burlov A.⁴, Revinskii Y.², Shcherbakov I.¹, Raspopova E.¹
Afiliações:
1. Southern Federal University
2. Southern Scientific Center
3. Kurnakov Institute of General and Inorganic Chemistry
4. Institute of Physical and Organic Chemistry
Edição: Volume 87, Nº 1 (2017)
Páginas: 66-75
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/217872
DOI: https://doi.org/10.1134/S1070363217010121
ID: 217872

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Resumo

A new Schiff base ligand, 4-methyl-N-{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L)₂], [Zn(L)₂], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studied by quantum chemical methods, and its zinc and cadmium complexes have been found to exhibit luminescence properties.