A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties
- Authors: Popov L.D.1, Borodkin S.A.1, Tsaturyan A.A.1, Tupolova Y.P.1, Levchenkov S.I.2, Minin V.V.3, Burlov A.S.4, Revinskii Y.V.2, Shcherbakov I.N.1, Raspopova E.A.1
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Affiliations:
- Southern Federal University
- Southern Scientific Center
- Kurnakov Institute of General and Inorganic Chemistry
- Institute of Physical and Organic Chemistry
- Issue: Vol 87, No 1 (2017)
- Pages: 66-75
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217872
- DOI: https://doi.org/10.1134/S1070363217010121
- ID: 217872
Cite item
Abstract
A new Schiff base ligand, 4-methyl-N-{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L)2], [Zn(L)2], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studied by quantum chemical methods, and its zinc and cadmium complexes have been found to exhibit luminescence properties.
About the authors
L. D. Popov
Southern Federal University
Author for correspondence.
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
S. A. Borodkin
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
A. A. Tsaturyan
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
Yu. P. Tupolova
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
S. I. Levchenkov
Southern Scientific Center
Email: ldpopov@mail.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006
V. V. Minin
Kurnakov Institute of General and Inorganic Chemistry
Email: ldpopov@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
A. S. Burlov
Institute of Physical and Organic Chemistry
Email: ldpopov@mail.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
Yu. V. Revinskii
Southern Scientific Center
Email: ldpopov@mail.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006
I. N. Shcherbakov
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
E. A. Raspopova
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090