A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties


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Abstract

A new Schiff base ligand, 4-methyl-N-{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L)2], [Zn(L)2], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studied by quantum chemical methods, and its zinc and cadmium complexes have been found to exhibit luminescence properties.

About the authors

L. D. Popov

Southern Federal University

Author for correspondence.
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

S. A. Borodkin

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

A. A. Tsaturyan

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

Yu. P. Tupolova

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

S. I. Levchenkov

Southern Scientific Center

Email: ldpopov@mail.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006

V. V. Minin

Kurnakov Institute of General and Inorganic Chemistry

Email: ldpopov@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991

A. S. Burlov

Institute of Physical and Organic Chemistry

Email: ldpopov@mail.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090

Yu. V. Revinskii

Southern Scientific Center

Email: ldpopov@mail.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006

I. N. Shcherbakov

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

E. A. Raspopova

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090


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