Synthesis, characterization, biological activity, and DFT-reactivity assessment of Mn(II), Co(II), and Cu(II) complexes of a new N2O tridentate Schiff base
- Autores: Engin M.1, Demir S.1, Direkel Ş.1, Eymur S.1, Çay S.1, Güder A.1
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Afiliações:
- Giresun University
- Edição: Volume 86, Nº 12 (2016)
- Páginas: 2855-2861
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217050
- DOI: https://doi.org/10.1134/S1070363216120501
- ID: 217050
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Resumo
Three new homoleptic Schiff base: metal(II) complexes, bis{2-[(pyridin-2-yl) methylene-amino] naphthoxometal(II)} [M(npa)2], (M = Mn(II) (1), Co(II) (2), Cu(II) (3), npa is monoanion of 2-[(pyridin-2-yl)methyleneamino]naphthol), have been prepared and characterized by elemental analyses, FT–IR, 1H and 13C NMR, and HR-MS-TOF. Antimicrobial activity of the title compounds was tested against six standart bacteria and two standart fungi isolates by microdilution broth assay with Alamar Blue Dye. Biological activity of the complexes has been estimated by using Fukui reactivity indices and frontier molecular orbitals in the framework of conceptual density functional theory.
Sobre autores
M. Engin
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200
S. Demir
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200
Ş. Direkel
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200
S. Eymur
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200
S. Çay
Giresun University
Autor responsável pela correspondência
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200
A. Güder
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Turquia, Giresun, 28200