Synthesis, characterization, biological activity, and DFT-reactivity assessment of Mn(II), Co(II), and Cu(II) complexes of a new N2O tridentate Schiff base
- Авторлар: Engin M.1, Demir S.1, Direkel Ş.1, Eymur S.1, Çay S.1, Güder A.1
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Мекемелер:
- Giresun University
- Шығарылым: Том 86, № 12 (2016)
- Беттер: 2855-2861
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217050
- DOI: https://doi.org/10.1134/S1070363216120501
- ID: 217050
Дәйексөз келтіру
Аннотация
Three new homoleptic Schiff base: metal(II) complexes, bis{2-[(pyridin-2-yl) methylene-amino] naphthoxometal(II)} [M(npa)2], (M = Mn(II) (1), Co(II) (2), Cu(II) (3), npa is monoanion of 2-[(pyridin-2-yl)methyleneamino]naphthol), have been prepared and characterized by elemental analyses, FT–IR, 1H and 13C NMR, and HR-MS-TOF. Antimicrobial activity of the title compounds was tested against six standart bacteria and two standart fungi isolates by microdilution broth assay with Alamar Blue Dye. Biological activity of the complexes has been estimated by using Fukui reactivity indices and frontier molecular orbitals in the framework of conceptual density functional theory.
Авторлар туралы
M. Engin
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
S. Demir
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
Ş. Direkel
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
S. Eymur
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
S. Çay
Giresun University
Хат алмасуға жауапты Автор.
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
A. Güder
Giresun University
Email: seydahmet.cay@giresun.edu.tr
Түркия, Giresun, 28200
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