Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes
- Авторлар: Gusarova N.1, Verkhoturova S.1, Arbuzova S.1, Kazantseva T.1, Albanov A.1, Nalibaeva A.2, Bishimbaeva G.2, Apartsin K.3, Kireeva V.3, Trofimov B.1
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Мекемелер:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Sokol’skii Institute of Fuel
- Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
- Шығарылым: Том 88, № 4 (2018)
- Беттер: 705-712
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222133
- DOI: https://doi.org/10.1134/S107036321804014X
- ID: 222133
Дәйексөз келтіру
Аннотация
Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (–10 to 25°C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48–72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the 1H, 13C, 19F, and 31P NMR data.
Авторлар туралы
N. Gusarova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033
S. Verkhoturova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033
S. Arbuzova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033
T. Kazantseva
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033
A. Nalibaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Қазақстан, ul. Kunaeva 142, Almaty, 050010
G. Bishimbaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Қазақстан, ul. Kunaeva 142, Almaty, 050010
K. Apartsin
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Lermontova 134, Irkutsk, 664033
V. Kireeva
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Lermontova 134, Irkutsk, 664033
B. Trofimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Хат алмасуға жауапты Автор.
Email: boris_trofimov@irioch.irk.ru
Ресей, ul. Favorskogo 1, Irkutsk, 664033