Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes
- Авторы: Gusarova N.1, Verkhoturova S.1, Arbuzova S.1, Kazantseva T.1, Albanov A.1, Nalibaeva A.2, Bishimbaeva G.2, Apartsin K.3, Kireeva V.3, Trofimov B.1
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Учреждения:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Sokol’skii Institute of Fuel
- Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
- Выпуск: Том 88, № 4 (2018)
- Страницы: 705-712
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222133
- DOI: https://doi.org/10.1134/S107036321804014X
- ID: 222133
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Аннотация
Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (–10 to 25°C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48–72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the 1H, 13C, 19F, and 31P NMR data.
Об авторах
N. Gusarova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
S. Verkhoturova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
S. Arbuzova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
T. Kazantseva
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033
A. Nalibaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Казахстан, ul. Kunaeva 142, Almaty, 050010
G. Bishimbaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Казахстан, ul. Kunaeva 142, Almaty, 050010
K. Apartsin
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Lermontova 134, Irkutsk, 664033
V. Kireeva
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Lermontova 134, Irkutsk, 664033
B. Trofimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Автор, ответственный за переписку.
Email: boris_trofimov@irioch.irk.ru
Россия, ul. Favorskogo 1, Irkutsk, 664033