Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes
- 作者: Gusarova N.1, Verkhoturova S.1, Arbuzova S.1, Kazantseva T.1, Albanov A.1, Nalibaeva A.2, Bishimbaeva G.2, Apartsin K.3, Kireeva V.3, Trofimov B.1
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隶属关系:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Sokol’skii Institute of Fuel
- Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
- 期: 卷 88, 编号 4 (2018)
- 页面: 705-712
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222133
- DOI: https://doi.org/10.1134/S107036321804014X
- ID: 222133
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详细
Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (–10 to 25°C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48–72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the 1H, 13C, 19F, and 31P NMR data.
作者简介
N. Gusarova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
S. Verkhoturova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
S. Arbuzova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
T. Kazantseva
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
A. Nalibaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
哈萨克斯坦, ul. Kunaeva 142, Almaty, 050010
G. Bishimbaeva
Sokol’skii Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
哈萨克斯坦, ul. Kunaeva 142, Almaty, 050010
K. Apartsin
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Lermontova 134, Irkutsk, 664033
V. Kireeva
Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Lermontova 134, Irkutsk, 664033
B. Trofimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
编辑信件的主要联系方式.
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033