Structure and magnetic properties of 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one adducts with cobalt(II) salts
- Авторлар: Ivakhnenko E.1, Koshchienko Y.1, Chernyshev A.1, Knyazev P.1, Ivakhnenko T.1, Lyssenko K.1
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Мекемелер:
- Institute of Physical and Organic Chemistry
- Шығарылым: Том 86, № 7 (2016)
- Беттер: 1664-1670
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215719
- DOI: https://doi.org/10.1134/S1070363216070227
- ID: 215719
Дәйексөз келтіру
Аннотация
Complex formation reaction of redox-active 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one with cobalt(II) chloride leading to the dimeric adduct has been studied. UV spectroscopy studies have revealed the equilibrium of the formed adduct with dissociated form of the complex in the acetonitrile solution. In the presence of ethylene glycol, the complex formation with cobalt(II) perchlorate has afforded the high-spin trimolecular adduct. Crystal structure of the obtained adducts has been studied by means of X-ray diffraction analysis.
Негізгі сөздер
Авторлар туралы
E. Ivakhnenko
Institute of Physical and Organic Chemistry
Хат алмасуға жауапты Автор.
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090
Yu. Koshchienko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090
A. Chernyshev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090
P. Knyazev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090
T. Ivakhnenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090
K. Lyssenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Ресей, Stachki pr. 194/2, Rostov-on-Don, 344090