Structure and magnetic properties of 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one adducts with cobalt(II) salts
- 作者: Ivakhnenko E.1, Koshchienko Y.1, Chernyshev A.1, Knyazev P.1, Ivakhnenko T.1, Lyssenko K.1
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隶属关系:
- Institute of Physical and Organic Chemistry
- 期: 卷 86, 编号 7 (2016)
- 页面: 1664-1670
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215719
- DOI: https://doi.org/10.1134/S1070363216070227
- ID: 215719
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详细
Complex formation reaction of redox-active 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one with cobalt(II) chloride leading to the dimeric adduct has been studied. UV spectroscopy studies have revealed the equilibrium of the formed adduct with dissociated form of the complex in the acetonitrile solution. In the presence of ethylene glycol, the complex formation with cobalt(II) perchlorate has afforded the high-spin trimolecular adduct. Crystal structure of the obtained adducts has been studied by means of X-ray diffraction analysis.
作者简介
E. Ivakhnenko
Institute of Physical and Organic Chemistry
编辑信件的主要联系方式.
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090
Yu. Koshchienko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090
A. Chernyshev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090
P. Knyazev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090
T. Ivakhnenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090
K. Lyssenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
俄罗斯联邦, Stachki pr. 194/2, Rostov-on-Don, 344090