Structure and magnetic properties of 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one adducts with cobalt(II) salts
- Autores: Ivakhnenko E.1, Koshchienko Y.1, Chernyshev A.1, Knyazev P.1, Ivakhnenko T.1, Lyssenko K.1
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Afiliações:
- Institute of Physical and Organic Chemistry
- Edição: Volume 86, Nº 7 (2016)
- Páginas: 1664-1670
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215719
- DOI: https://doi.org/10.1134/S1070363216070227
- ID: 215719
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Resumo
Complex formation reaction of redox-active 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one with cobalt(II) chloride leading to the dimeric adduct has been studied. UV spectroscopy studies have revealed the equilibrium of the formed adduct with dissociated form of the complex in the acetonitrile solution. In the presence of ethylene glycol, the complex formation with cobalt(II) perchlorate has afforded the high-spin trimolecular adduct. Crystal structure of the obtained adducts has been studied by means of X-ray diffraction analysis.
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Sobre autores
E. Ivakhnenko
Institute of Physical and Organic Chemistry
Autor responsável pela correspondência
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090
Yu. Koshchienko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090
A. Chernyshev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090
P. Knyazev
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090
T. Ivakhnenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090
K. Lyssenko
Institute of Physical and Organic Chemistry
Email: e.ivakhnenko@ipoc.sfedu.ru
Rússia, Stachki pr. 194/2, Rostov-on-Don, 344090