Colloid and Nanosized Catalysts in Organic Synthesis: XXII. Hydrogenation of Cycloolefins Catalyzed by Immobilized Transition Metals Nanoparticles in a Three-Phase System
- Authors: Nebykov D.N.1, Popov Y.V.1, Mokhov V.M.1, Latyshova S.E.1, Shcherbakova K.V.1, Nemtseva N.V.1, Shishkin E.V.1
-
Affiliations:
- Volgograd State Technical University
- Issue: Vol 89, No 10 (2019)
- Pages: 1985-1989
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223104
- DOI: https://doi.org/10.1134/S1070363219100013
- ID: 223104
Cite item
Abstract
The processes of unsaturated cyclic hydrocarbons hydrogenation in a three-phase gas-liquid-solid catalyst system in the presence of nanostructured nickel, cobalt, or iron catalysts in a flow reactor at 130°C and atmospheric pressure have studied. RX3Extra activated carbon, γ-Al2O3, NaX zeolite, and Purolite CT-175 cation-exchange resin have been used as supports; NaBH4 and NH2NH2·H2O were used as reducing agents. The catalytic activity of supported nanoparticles and their selectivity with respect to the product of exhaustive hydrogenation have been investigated.
Keywords
About the authors
D. N. Nebykov
Volgograd State Technical University
Author for correspondence.
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
Yu. V. Popov
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
V. M. Mokhov
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
S. E. Latyshova
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
K. V. Shcherbakova
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
N. V. Nemtseva
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131
E. V. Shishkin
Volgograd State Technical University
Email: nervwho@gmail.com
Russian Federation, pr. Lenina 28, Volgograd, 400131