Colloid and Nanosized Catalysts in Organic Synthesis: XXII. Hydrogenation of Cycloolefins Catalyzed by Immobilized Transition Metals Nanoparticles in a Three-Phase System
- Autores: Nebykov D.1, Popov Y.1, Mokhov V.1, Latyshova S.1, Shcherbakova K.1, Nemtseva N.1, Shishkin E.1
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Afiliações:
- Volgograd State Technical University
- Edição: Volume 89, Nº 10 (2019)
- Páginas: 1985-1989
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223104
- DOI: https://doi.org/10.1134/S1070363219100013
- ID: 223104
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Resumo
The processes of unsaturated cyclic hydrocarbons hydrogenation in a three-phase gas-liquid-solid catalyst system in the presence of nanostructured nickel, cobalt, or iron catalysts in a flow reactor at 130°C and atmospheric pressure have studied. RX3Extra activated carbon, γ-Al2O3, NaX zeolite, and Purolite CT-175 cation-exchange resin have been used as supports; NaBH4 and NH2NH2·H2O were used as reducing agents. The catalytic activity of supported nanoparticles and their selectivity with respect to the product of exhaustive hydrogenation have been investigated.
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Sobre autores
D. Nebykov
Volgograd State Technical University
Autor responsável pela correspondência
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
Yu. Popov
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
V. Mokhov
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
S. Latyshova
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
K. Shcherbakova
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
N. Nemtseva
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131
E. Shishkin
Volgograd State Technical University
Email: nervwho@gmail.com
Rússia, pr. Lenina 28, Volgograd, 400131