Phosphorylation of 1,4:3,6-Dianhydro- d -sorbitol

K. L. Anfilov; G. I. Kurochkina; G. S. Bratash; M. K. Grachev

doi:10.1134/S107036321905013X

Phosphorylation of 1,4:3,6-Dianhydro-d-sorbitol

Authors: Anfilov K.L.¹, Kurochkina G.I.², Bratash G.S.², Grachev M.K.²
Affiliations:
1. Kaluga Branch of the N.E. Bauman Moscow State Technical University
2. Institute of Biology and Chemistry
Issue: Vol 89, No 5 (2019)
Pages: 939-943
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222904
DOI: https://doi.org/10.1134/S107036321905013X
ID: 222904

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Abstract

Regioselective mono- and diphosphorylation of 1,4:3,6-dianhydro-d-sorbitol containing two hydroxyl groups differing in steric availability has been studied. The nature of the amine acting as activator and acceptor of hydrogen chloride have had significant impact on the direction of phosphorylation and the structure of the resulting products.