Phosphorylation of 1,4:3,6-Dianhydro-d-sorbitol


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Abstract

Regioselective mono- and diphosphorylation of 1,4:3,6-dianhydro-d-sorbitol containing two hydroxyl groups differing in steric availability has been studied. The nature of the amine acting as activator and acceptor of hydrogen chloride have had significant impact on the direction of phosphorylation and the structure of the resulting products.

About the authors

K. L. Anfilov

Kaluga Branch of the N.E. Bauman Moscow State Technical University

Author for correspondence.
Email: kanfilov@yandex.ru
Russian Federation, ul. Bazhenova 2, Kaluga, 248000

G. I. Kurochkina

Institute of Biology and Chemistry

Email: kanfilov@yandex.ru
Russian Federation, Moscow

G. S. Bratash

Institute of Biology and Chemistry

Email: kanfilov@yandex.ru
Russian Federation, Moscow

M. K. Grachev

Institute of Biology and Chemistry

Email: kanfilov@yandex.ru
Russian Federation, Moscow


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