The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents
- Authors: Maltceva O.V.1, Mamardashvili N.Z.1
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Affiliations:
- Krestov Institute of Solutions Chemistry
- Issue: Vol 87, No 6 (2017)
- Pages: 1175-1183
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220187
- DOI: https://doi.org/10.1134/S1070363217060123
- ID: 220187
Cite item
Abstract
The complex formation of β-octaethylporphyrin, β-octaethyl-meso-monophenylporphyrin, β-octaethyl-meso-tetraphenylporphyrin, meso-diphenylporphyrin, meso-triphenylporphyrin, and meso-tetraphenylporphyrin with Zn(II), Cu(II), Co(II), and Mn(II) acetates and chlorides in dimethylformamide, dimethylsulfoxide, pyridine, acetic acid, and a chloroform–methanol 1 : 1 mixture has been studied by means of spectrophotometry. The observed regulations are in line with the concept of chemical reactivity of the N–H bonds in porphyrins of different complexity.
Keywords
About the authors
O. V. Maltceva
Krestov Institute of Solutions Chemistry
Author for correspondence.
Email: olga_toldina@mail.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
N. Zh. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: olga_toldina@mail.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045