The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents
- Авторлар: Maltceva O.1, Mamardashvili N.1
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Мекемелер:
- Krestov Institute of Solutions Chemistry
- Шығарылым: Том 87, № 6 (2017)
- Беттер: 1175-1183
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220187
- DOI: https://doi.org/10.1134/S1070363217060123
- ID: 220187
Дәйексөз келтіру
Аннотация
The complex formation of β-octaethylporphyrin, β-octaethyl-meso-monophenylporphyrin, β-octaethyl-meso-tetraphenylporphyrin, meso-diphenylporphyrin, meso-triphenylporphyrin, and meso-tetraphenylporphyrin with Zn(II), Cu(II), Co(II), and Mn(II) acetates and chlorides in dimethylformamide, dimethylsulfoxide, pyridine, acetic acid, and a chloroform–methanol 1 : 1 mixture has been studied by means of spectrophotometry. The observed regulations are in line with the concept of chemical reactivity of the N–H bonds in porphyrins of different complexity.
Негізгі сөздер
Авторлар туралы
O. Maltceva
Krestov Institute of Solutions Chemistry
Хат алмасуға жауапты Автор.
Email: olga_toldina@mail.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: olga_toldina@mail.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153045