The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents
- Autores: Maltceva O.1, Mamardashvili N.1
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Afiliações:
- Krestov Institute of Solutions Chemistry
- Edição: Volume 87, Nº 6 (2017)
- Páginas: 1175-1183
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220187
- DOI: https://doi.org/10.1134/S1070363217060123
- ID: 220187
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Resumo
The complex formation of β-octaethylporphyrin, β-octaethyl-meso-monophenylporphyrin, β-octaethyl-meso-tetraphenylporphyrin, meso-diphenylporphyrin, meso-triphenylporphyrin, and meso-tetraphenylporphyrin with Zn(II), Cu(II), Co(II), and Mn(II) acetates and chlorides in dimethylformamide, dimethylsulfoxide, pyridine, acetic acid, and a chloroform–methanol 1 : 1 mixture has been studied by means of spectrophotometry. The observed regulations are in line with the concept of chemical reactivity of the N–H bonds in porphyrins of different complexity.
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Sobre autores
O. Maltceva
Krestov Institute of Solutions Chemistry
Autor responsável pela correspondência
Email: olga_toldina@mail.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045
N. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: olga_toldina@mail.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153045